a, \(\left\{{}\begin{matrix}n_{Ba^{2+}}=4.10^{-3}\left(mol\right)\\n_{Na^+}=3.10^{-3}\left(mol\right)\\n_{OH^-}=0,011\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow\left\{{}\begin{matrix}\left[Ba^{2+}\right]=\dfrac{4.10^{-3}}{0,2+0,3}=0,008M\\\left[Na^+\right]=\dfrac{3.10^{-3}}{0,2+0,3}=0,006M\\\left[OH^-\right]=\dfrac{0,011}{0,2+0,3}=0,022M\end{matrix}\right.\)

b, Để trung hòa dung dịch A thì:

\(n_{H^+}=n_{OH^-}\)

\(\Leftrightarrow0,01.V_{ddHCl}=\left(0,02.2+0,01\right).0,2\)

\(\Leftrightarrow V_{ddHCl}=1\left(l\right)\)

cần lời giải chi tiết ạ

\(n_{H_2SO_4}=1.0,2=0,2(mol)\\ H_2SO_4+BaCl_2\to BaSO_4\downarrow+2HCl\\ \Rightarrow n_{BaSO_4}=n_{BaCl_2}=0,2(mol)\\ a,m_{BaSO_4}=0,2.233=46,6(g)\\ b,V_{dd_{BaCl_2}}=\dfrac{0,2}{1,5}\approx 0,13(l)\\ c,n_{HCl}=0,4(mol)\\ \Rightarrow C_{M_{HCl}}=\dfrac{0,4}{0,2+0,13}\approx 1,21M\)

\(d,\) Dd sau p/ứ là HCl nên làm quỳ tím hóa đỏ

\(n_{H_2SO_4}=0,2.1=0,2\left(mol\right)\\ H_2SO_4+BaCl_2\rightarrow BaSO_4+2HCl\\ n_{BaCl_2}=n_{BaSO_4}=n_{H_2SO_4}=0,2\left(mol\right)\\ n_{HCl}=2.0,2=0,4\left(mol\right)\\ a,m_{\downarrow}=m_{BaSO_4}=0,2.233=46,6\left(g\right)\\ b,V_{\text{dd}BaCl_2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)\\ c,C_{M\text{dd}HCl}=\dfrac{0,4}{\dfrac{2}{15}+0,2}=1,2\left(M\right)\\ d,V\text{ì}.c\text{ó}.\text{dd}.HCl\Rightarrow Qu\text{ỳ}.ho\text{á}.\text{đ}\text{ỏ}\)

200ml = 0,2l

\(n_{H2SO4}=1.0,2=0,2\left(mol\right)\)

Pt : \(BaCl_2+H_2SO_4\rightarrow BaSO_4+2HCl|\)

           1           1                  1              2

          0,2        0,2               0,2           0,4

a) \(n_{BaSO4}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

⇒ \(m_{BaSO4}=0,2.233=46,6\left(g\right)\)

b) \(n_{BaCl2}=\dfrac{0,2.1}{1}=0,2\left(mol\right)\)

\(V_{ddBaCl2}=\dfrac{0,2}{1,5}=\dfrac{2}{15}\left(l\right)=133,33\left(ml\right)\)

c) \(n_{HCl}=\dfrac{0,2.2}{1}=0,4\left(mol\right)\)

\(V_{ddspu}=0,2+\dfrac{2}{15}=\dfrac{1}{3}\left(l\right)\)

\(C_{M_{ddHCl}}=\dfrac{0,4}{\dfrac{1}{3}}=1,2\left(M\right)\)

d) Cho quỳ tím vào dung dịch sau phản ứng , quỳ tím hóa đỏ. Vì dung dịch thu được sau phản ứng có HCl là axit

 Chúc bạn học tốt

a, \(n_{H^+}=n_{OH^-}=9.10^{-3}\left(mol\right)\Rightarrow C_{M\left(H_2SO_4\right)}=\dfrac{\dfrac{9.10^{-3}}{2}}{0,05}=0,09M\)

b, \(\left[SO_4^{2-}\right]=\dfrac{4,5.10^{-3}}{0,05+0,15}=0,6M\)

\(\left[Na^+\right]=\dfrac{0,15.0,06}{0,05+0,15}=0,045M\)

\(\left[H^+\right]=\left[OH^-\right]=\dfrac{9.10^{-3}}{0,05+0,15}=0,045M\)

\(n_{OH^-}=0,5.0,2+0,2.2.0,3=0,22\left(mol\right)\Rightarrow\left[OH^-\right]=\dfrac{0,22}{0,5}=0,44M\)

\(n_{Na^+}=0,5.0,2=0,1\left(mol\right)\Rightarrow\left[Na^+\right]=\dfrac{0,1}{0,5}=0,2M\)

\(n_{Ba^{2+}}=0,2.0,3=0,06\left(mol\right)\Rightarrow\left[Ba^{2+}\right]=\dfrac{0,06}{0,5}=0,12M\)

nCa(OH)2 = 0,07(mol)

=> CM Ca(OH)2 = n/V = 0,07 / 0,3 = 0,233(M)

Số mol Ca(OH)2 = 0,07 mol

Nồng độ mol của dd thu đc C= 0,07/0,3= 0,233(M)

a, \(n_{Fe}=\dfrac{8,4}{56}=0,15\left(mol\right)\)

\(n_{HCl}=0,2.2=0,4\left(mol\right)\)

PT: \(Fe+2HCl\rightarrow FeCl_2+H_2\)

Xét tỉ lệ: \(\dfrac{0,15}{1}< \dfrac{0,4}{2}\), ta được HCl dư.

Theo PT: \(n_{H_2}=n_{Fe}=0,15\left(mol\right)\Rightarrow V_{H_2}=0,15.22,4=3,36\left(l\right)=3360\left(ml\right)\)

b, Theo PT: \(\left\{{}\begin{matrix}n_{FeCl_2}=n_{Fe}=0,15\left(mol\right)\\n_{HCl\left(pư\right)}=2n_{Fe}=0,3\left(mol\right)\end{matrix}\right.\)

\(\Rightarrow n_{HCl\left(dư\right)}=0,4-0,3=0,1\left(mol\right)\)

\(\Rightarrow\left\{{}\begin{matrix}C_{M_{FeCl_2}}=\dfrac{0,15}{0,2}=0,75\left(M\right)\\C_{M_{HCl\left(dư\right)}}=\dfrac{0,1}{0,2}=0,5\left(M\right)\end{matrix}\right.\)

c, Ta có: \(m_{ddHCl}=1,25.200=250\left(g\right)\)

⇒ m _{dd sau pư} = 8,4 + 250 - 0,15.2 = 258,1 (g)

\(\Rightarrow\left\{{}\begin{matrix}C\%_{FeCl_2}=\dfrac{0,15.127}{258,1}.100\%\approx7,38\%\\C\%_{HCl\left(dư\right)}=\dfrac{0,1.36,5}{258.1}.100\%\approx1,41\%\end{matrix}\right.\)